Calculate the electrical conductivity of electrolyte solutions with temperature correction
Enter concentration, molar conductivity, and temperature. Use presets for common electrolytes.
Ion Mobility
Conductivity depends on the number and speed of ions in solution.
Thermal Effect
Higher temperatures increase ion mobility, thus conductivity.
Basic Equation
κ = c × Λ
κ = c × Λ × (1 + 0.02(T - 25))
Where: κ = conductivity (S/m), c = concentration (mol/L), Λ = molar conductivity (S·m²/mol), T = temperature (°C)
κ = c × Λ at 25°C
2% increase per °C above 25°C
Water quality, batteries, electrochemistry
Electrical conductivity is a key property in chemistry that determines how well a solution conducts electricity through ion movement. Our Conductivity Calculator helps you compute conductivity for electrolyte solutions, accounting for concentration, molar conductivity, and temperature effects. Perfect for students, researchers, and professionals in electrochemistry, environmental science, and industrial applications.
Conductivity (κ) measures the ability of an electrolyte solution to conduct electric current, primarily due to free-moving ions.
It depends on ion concentration, charge, and mobility. Higher ion count and faster movement increase conductivity.
Temperature affects conductivity: ions move faster in warmer solutions, typically increasing κ by ~2% per °C.
Units: Siemens per meter (S/m). Used in water purity testing, battery design, and chemical analysis.
The fundamental relationship between conductivity, concentration, and molar conductivity is:
κ = c × Λ Where: κ = Specific conductivity (S/m) c = Concentration (mol/L or mol/m³, note unit consistency) Λ = Molar conductivity (S·m²/mol) Temperature Correction (approximate): κ_T = κ_25 × [1 + α (T - 25)] α ≈ 0.02 /°C for most aqueous solutions
Example 1: Sodium Chloride (NaCl) Solution
Concentration c = 0.1 mol/L
Molar Conductivity Λ = 100 S·m²/mol (approximate for dilute NaCl)
Temperature T = 25°C
κ = 0.1 × 100 = 10 S/m
👉 No temperature correction needed. Conductivity = 10.00 S/m
Example 2: Potassium Hydroxide (KOH) at Elevated Temperature
Concentration c = 0.05 mol/L
Molar Conductivity Λ = 150 S·m²/mol
Temperature T = 30°C
Base κ = 0.05 × 150 = 7.5 S/m
Temp factor = 1 + 0.02 × (30 - 25) = 1.10
κ_corrected = 7.5 × 1.10 = 8.25 S/m
👉 Conductivity = 8.25 S/m (10% higher due to temperature)
Q1. What is the difference between conductivity and molar conductivity?
Conductivity (κ) is the total ability of the solution to conduct current, while molar conductivity (Λ) is the conductivity per mole of electrolyte, independent of concentration in ideal cases.
Q2. Why does temperature affect conductivity?
Higher temperatures increase the kinetic energy of ions, enhancing their mobility and thus the solution's conductivity. The effect is approximately linear with a 2% increase per °C for aqueous solutions.
Q3. What are typical units for conductivity?
The SI unit is Siemens per meter (S/m). In practice, microsiemens per centimeter (µS/cm) is common for water quality measurements.
Q4. Is this calculator accurate for all solutions?
It's optimized for dilute aqueous electrolytes. For concentrated solutions or non-aqueous media, more advanced models accounting for ion interactions may be needed.
For further understanding and validation of the formulas used above, we recommend exploring these authoritative resources: